Volume 301
Main Index

Issue 1, Pages 1-130 (18 January 1986)

Metal ions in biological systems. Vol. 18. Circulation of metals in the environment : Edited by H. Sigel, New York, Marcel Dekker, 1984, 432 pages, $79.75 or SFr 212. ISBN 0-8247-7226-1. Page C12 Michael A. Ford Smith

Ligand transfer reactions between different metallic sites. Crystal structure of [(C5H5)2Co4(CO)5(F3CCCCF3)] Pages C1-C4 Rene Rumin, Pierre Courtot, Jacques E. Guerchais, François Y. Pétillon, Lubica Manojlovi-Muir and, Kenneth W. Muir

Organometallic chemistry reviews; annual surveys: Si, Sb, Bi, Mn, Tc, Re, heteronuclear complexes (Journal of organometallic chemistry library 17) : Edited by R.B. King and J.P. Oliver, Elsevier, Amsterdam, 1985, 577 pages, DFl. 450, US $166,75, ISBN 0-444-42515-2. Page C15 Paul D. Lickiss

Homogenous catalysis with compounds of rhodium and iridium : By Ronald S. Dickson, D. Reidel Publishing Company, 1985, xv + 278 pages, £37.50, ISBN 90-277-1880-6. Page C13 Penny A. Chaloner

Synthesis, NMR, and structural characterization of the [Ni9Pt3(CO)21H4-n]n− (n = 4, 3, 2) anionic clusters Pages C5-C8 Alessandro Ceriotti, Francesco Demartin, Giuliano Longoni, Mario Manassero, Gianluigi Piva, Giampietro Piro, Mirella Sansoni, Brian T. Heaton

Synthese und reaktivität von dienylmetall-verbindungen, : XXVI. C5H5Ni(PH3)I und [C5H5Ni(PH3)2]BF4, isolierbare phosphankomplexe des zweiwertigen nickels Pages C9-C11 N. Kuhn, M. Winter

Author index Page C16

Lithium - current applications in science, medicine, and technology : Edited by R.O. Bach, Wiley-Interscience, New York, Chichester, Brisbane, Toronto, Singapore, 1985 xvii + 422 pages, £92.50. ISBN 0-471-80073-2. Page C14 Kenneth R. Seddon

Metallomethanes : XII. Vibrational spectra and force fields of methylmercurimethanes Pages 1-13 Janos Mink, Dietrich K. Breitinger, Wolfram Kress

Silyl-nitrogen compounds : I. Reactions of dilithium bis(trimethylsilyl)hydrazine with group IV halides Pages 15-25 Sham Kumar Vasisht, Mohini Sood, Nirupma Sood, Gursharan Singh

Über polygermane : XIV. Polygermane als nebenprodukte der Grignard-reaktion von PhMgBr mit GeCl4 Pages 27-40 Stefan Roller, Dietolf Simon, Martin Dräger

Ein beitrag zur hydrolyse von titanocendichlorid: Darstellung, struktur und eigenschaften des dreikernigen, Sauerstoff-zentrierten, basischen carboxylatokomplexes [Ti3(μ3-O)(μ2-OH)3(μ2-HCOO)3(η5-C5H5)3]+ HCOO− · 2HCOOH Pages 41-48 Karl Döppert, Ulf Thewalt

The W(μ-N2)W system : II. Crystal structure of [(η5-C5Me5)W(CH3)3]2(μ-N2), AN organotungsten(VI) complex containing a W=N---N=W core Pages 49-59 Melvyn Rowen Churchill, Yong-Ji Li

Stabilisation de molecules hyperactives par complexation: Le formyl-2 butadiene fer-tricarbonyle. Preparation, dedoublement et reactivite Pages 61-77 Michel Franck-Neumann, Daniel Martina, Marie-Paule Heitz

Carbonylcobalt(I) complexes. The crystal and molecular structure of [Co(CO)(dppm)2]ClO4 Pages 79-90 C. Carriedo, P. Gomez-Sal, P. Royo, S. Martinez-Carrera and, S. Garcia-Blanco

Pyridine induced disproportionation reaction of Co2(CO)8 in THF: Homonuclear ion pairs and dihydrogen activation Pages 91-97 G. Fachinetti, G. Fochi, T. Funaioli

Formation and crystal structure of MeIr(CO)(PPh3)2(MeCO2CH=CHCO2Me). Comparison of the structures of analogous alkene and alkyne complexes Pages 99-108 Melvyn Rowen Churchill, James C. Fettinger, Wayne M. Rees, Jim D. Atwood

Asymmetrically bonded π ligands : I. Hinging away from metal of substituted allyls: Syntheses of 1-syn-methyl and -phenyl complexes, and the molecular structures of (η-1-Ph-C3H4)Pd(tmeda)]BF4, [(η-C5H5)Pd(η-1-Ph-C3H4)], and [(phen)Mo(CO)2(NCS)(η-1-Ph-C3H4)] at 185 K Pages 109-130 Nicholas W. Murrall, Alan J. Welch

Issue 2, Pages 131-267 (25 February 1986)

Methods for the Oxidation of Organic Compounds; Alkanes, Alkenes, Alkynes and Arenes : By Alan H. Haines, Academic Press, London, New York, 1985, xix + 388 pages, £75.00, $83.00, ISBN 012-3155-010. Pages C41-C42 Penny A. Chaloner

The electronic structures of [(C5H4XC6H5)Cr(CO)3]− and (C6H5XC5H4)Mn(CO)3, (X = −, CO, CH2, C2H2) Pages C31-C34 Noel J. Fitzpatrick, Niall J. Gogan, Pardeep K. Sayal

Fundamental and Technological Aspects of Organo-f-Element Chemistry; : Edited by T.J. Marks and I.L. Fragalà, NATO ASI Series C: Mathematical and Physical Sciences Vol. 155, D. Reidel Publishing Company, Dordrecht, Boston, Lancaster, 1985, xiv + 414 pages, £44.50 (U.S. $56.00), ISBN 90-277-2053-3. Pages C38-C39 Kenneth R. Seddon

Palladium-catalyzed carbonylative cross-coupling of organoboranes with aryl iodides or benzyl halides in the presence of bis(acetylacetonato)zinc(II) Pages C17-C20 Yoshiaki Wakita, Tomoyuki Yasunaga, Masahiro Akita, Masaharu Kojima

Landolt-Börnstein. Numerical Data and Functional Relationships in Science and Technology. New series. Group II. Atomic and Molecular Physics. Supplement 4 (1973, 1974) to Volume 12, Magnetic Properties of Coordination and Organometallic Transition Metal Compounds. Sub-Volume b. Electron Paramagnetic Resonance : By E. König and G. König. Springer Verlag, Berlin etc., 1984, xxxix + 352 pages. DM 710. ISBN 3-540-13018-7. Page C38 Colin Eaborn

Electrochemistry, Volume 10 : (Senior Reporter: D. Pletcher), A Specialist Periodical Report of the Royal Society of Chemistry, London, 1985, x + 214 pages, £66.00 ($119.00). ISBN 0-85186-087-7. Pages C40-C41 Kenneth R. Seddon

The first example of [2+2] cycloaddition of Me4Ge2 to multiple bonds. The synthesis of Δ1,7-2,2,6,6,8,8,9,9-octa-methyl-4-thia-8,9-digermabicyclo[5.2.0]Nonene Pages C21-C22 O. M. Nefedov, M. P. Egorov, A. M. Gal'minas, S. P. Kolesnikov, A. Krebs and, J. Berndt

Houben-Weyl Methoden der Organischen Chemie, Organische Schwefel-Verbindungen 4th edition, Volume E11, parts 1 and 2 : Edited by D. Klamann, Georg Thieme Verlag, 1985, xxiv + 1821 pages, DM 1950. Pages C42-C43 Penny A. Chaloner

High-resolution 207Pb NMR of solid organolead compounds Pages C23-C26 José R. Ascenso, Robin K. Harris, Pierre Granger

Inorganic Syntheses, Volume 23 : Edited by S. Kirschner, Wiley-Interscience, New York, Chichester, Brisbane, Toronto, Singapore, 1985, xiii + 257 pages, £40.90. ISBN 0-471-81873-9. Pages C39-C40 Kenneth R. Seddon

Author Index Page C44

A high-nuclear carbonylphosphine cluster of palladium, Pd23(CO)22(PEt3)10 Pages C35-C37 E. G. Mednikov, N. K. Eremenko, Yu. L. Slovokhotov and, Yu. T. Struchkov

Cobalt-catalyzed low pressure double carbonylation of aryl and secondary benzyl halides Pages C27-C30 F. Francalanci, E. Bencini, A. Gardano, M. Vincenti, M. Foà

Hydrogenosilanes: Pentacoordination and pseudorotation Pages 131-135 Jacqueline Boyer, Robert J. P. Corriu, Agapit Kpoton, Muhammad Mazhar, Monique Poirier, Gerard Royo

The reaction of trichlorosilane with enamines Pages 137-144 Dudley C. Snyder

Organometalloidal derivatives of the transition metals : XI. Synthesis and crystal structures of Ph3GeSiMe3 and Ph3GeSiMe2Fe(CO)2(η5-C5H5) Pages 145-151 Lászlá Párkányi, Carlos Hernandez, Keith H. Pannell

5-germaspiro[4.4]nona-2,7-dienes Pages 153-160 Pierre Mazerolles, Fabienne Gregoire

The facile isomerization of benzo[8,9]bicyclo[5.2.0]nona-2,4,8-triene to benzo[7,8]bicyclo[4.2.1]nona-2,4,7-triene promoted by L3M(CO)3 complexes (M = Cr, Mo, W). The crystal structure of the tricarbonyl complex of benzo[7,8]bicyclo[4.2.1]nona-2,4,7-triene Pages 161-171 Piero Berno, Alberto Ceccon, Francesca Daprà, Alessandro Gambaro, Alfonso Venzo, Paolo Ganis, Giovanni Valle

Optically active monosubstituted cymantrene derivatives. Relationship of chiroptical characteristics with absolute configuration of the compounds Pages 173-182 N. M. Loim, M. V. Laryukova, P. V. Kondrat'ev, Z. N. Parnes

Koordination von 1,4-diaza-1,3-dienen (dad) an carbonyldieisen fragmente : III. Unsymmetrisch substituierte diazabutadiene und 1H-NMR-spektroskopische identifizierung der regioisomeren (dad)Fe2(CO)6-komplexe von t-Bu-N=CH-CH=N-i-Pr Pages 183-193 Hans-Werner Frühauf, Joachim Breuer

Transition-metal complexes with σ-bonded fluorine-containing groups : VII. Intramolecular cis-trans isomerization of bis-(perfluoroalkyl)iron tetracarbonyls Pages 195-201 S. I. Vdovenko, I. I. Guerus, Yu. L. Yagupolskii

A cyclometallated analogue of tris(2,2′-bipyridine)ruthenium(II) Pages 203-208 Edwin C. Constable, Jeremy M. Holmes

Rhodium(I)-mono- und -diazadienkomplexe, synthese, spektroskopische charakterisierung, oxidative additionsreaktionen und einsatz in der homogenen katalyse zur hydrosilylierung Pages 209-226 Monika Brockmann, Heindirk tom Dieck, Jürgen Klaus

Decomposition of [NiRR′L2] complexes induced by bromine or anodic oxidation Pages 227-236 Juan M. Coronas, Guillermo Muller, Mercedes Rocamora

Reactions of trans-[Pt(H2){P(C6H11)3}2] with heterocumulenes. The crystal and molecular structure of trans-[Pt{P(C6H11)3}2(H){OCH=C(C6H5)2}] Pages 237-245 A. Musco, W. Porzio, S. Destri, G. Gatti, A. Grassi and, P. Longo

Ethoxyacetylene: A useful building block for the organocopper(I) mediated synthesis of 1,4-diketones Pages 247-255 P. Wijkens, P. Vermeer

Steric consequence of the diastereoselective addition of chiral lithium 2-(1-dimethylaminoethyl)phenyl cuprates to some enones Pages 257-267 Staffan Andersson, Susan Jagner, Martin Nilsson, Fabio Urso

Issue 3, Pages 269-410 (4 March 1986)

Synthesis of a vinylcarbynetetrairon complex. Crystal and molecular structure of [(C5H5)2(CO)2Fe2(μ-CO)]2- (μ-C5H3)+BF4− Pages C55-C58 Charles P. Casey, Mark S. Konings, Kenneth J. Haller

η4,3-butadien-tris(triethylphosphan)eisen(0): Ein komplex zur fixierung von alkenen oder alkinen Pages C59-C61 Heinz Hoberg, Klaus Jenni

Subject Index Pages C71-C76

Hydrogenation Methods : Paul N. Rylander, Academic Press, London, New York, 1985, xv + 193 pages, £40. ISBN 0126053650. Pages C67-C68 Penny A. Chaloner

Rate-structure correlations for migratory CO insertion. Steric acceleration for the octahedral iron(II) case Pages C49-C54 C. R. Jablonski, Y. -P. Wang

Transition Metal Chemistry, Volume 9 : Edited by G.A. Melson and B.N. Figgis, Marcel Dekker, Inc., New York and Basel, 1985, iv + 312 pages, $65.00 (U.S.A. and Canada), $78.00 (elsewhere). ISBN 0-8247-7188-5. Pages C66-C67 Kenneth R. Seddon, Elaine A. Seddon

Gmelin handbook of inorganic chemistry : 8th Edition, Th — Thorium, Supplement Volume D2: Solvent Extraction, Springer Verlag, Berlin, Heidelberg, New York, Tokyo, 1985, xiv + 260 pages, DM 987, ISBN 3-540-93520-7. Page C65 Kenneth R. Seddon

Author Index Pages C69-C70

Nickel-catalyzed coupling of activated alkenes with organic halides Pages C62-C64 G. P. Boldrini, D. Savoia, E. Tagliavini, C. Trombini, A. Umani Ronchi

Reactivity of zirconocene and hafnocene dihydrides towards elemental selenium and sulfur. Strong evidence for insertion of a chalcogen unit into the metal—hydrogen bond Pages C45-C48 Mohammed Fahim, Gérard Tainturier

[Hg3{HC(PPh2)3}(OAc)n(O3SCF3)mn + m = 6: Complexes containing an acidic carbon Pages 269-272 Maria Lusser, Paul Peringer

Crystal and molecular structure of 13,13-dimethyl-8,13-dihydro-5H-Dibenzo[d, g][1.2.6]diselenagermonine and 13,13-diphenyl-8,13-dihydro-5H-dibenzo[d, g][1.2.6]diselenasilonine Pages 273-281 V. E. Shklover, Yu. E. Ovchinnikov, Yu. T. Struchkov, V. I. Rokitskaya, O. G. Rodin, V. F. Traven', B. I. Stepanov and, M. Yu. Aismont

Molecular rearrangement of Me5C5(Cl)Ge→ W(CO)5 Pages 283-288 Peter Jutzi, Bernd Hampel

Optisch aktive phosphine durch asymmetrische substitution prochiraler, homochiral substituierter phosphonite Pages 289-297 J. Neuffer, W. J. Richter

Carbonylkomplexe “früher” übergangsmetalle: Darstellung und struktur von Cp2Zr(CO)[P(OCH3)3] Pages 299-312 Gerhard Erker, Ulrich Dorf, Carl Krüger, Klaus Angermund

Kinetics of the reactions of methoxide ion with tricarbonyl-η-cycloheptatrienyl salts of chromium, molybdenum and tungsten Pages 313-319 Paul Powell, Michael Stephens, Kamla H. Yassin

Tricarbonyl(η6-cyclophane)molybdenum complexes and their geometry-dependent 13C NMR behavior Pages 321-327 Michiko Takamori, Nobuo Mori

Ring- versus metal-hydride deprotonation in cis-(η5-C5H5)(CO)2Re(SiPh3)H: A ROUTE TO cis- and trans-(η5-C5H4(SiPh3))(CO)2ReH2 Pages 329-335 P. Pasman, J. J. M. Snel

Reactions of coordinated cyclic polyolefins. The mechanism of the pericyclic [4,4]-sigmahaptotropic rearrangement; a kinetic study. Crystal structure of tricarbonyl[(2,3,4,5-η)bicyclo[4.2.1]nona-2,4-diene-7,7,8,8-tetracarbonitrile]iron Pages 337-348 Zeev Goldschmidt, Hugo E. Gottlieb, Elisheva Genizi, Drora Cohen, Israel Goldberg

Synthesis and structure of bis(μ-cyclohexene-2-ylthio)-μ4-thiododecacarbonyltetrairon Pages 349-354 B. I. Kolobkov, N. S. Nametkin, V. D. Tyurin, A. I. Nekhaev, G. G. Aleksandrov, M. T. Tashev and, H. B. Dustov

Triferrocenyl-komplexe von wolfram(VI): Molekülstruktur im festkörper und dynamisches verhalten in Lösung von triferrocenyl-ferrocenoxy-oxo-wolfram, WO(OFc)Fc3 Pages 355-367 Max Herberhold, Heidemarie Kniesel, Ludwig Haumaier, Ulf Thewalt

Bis-olefin-rhodium(I) complexes of a tripod ligand with an O,O,O-donor set Pages 369-374 M. Scotti, M. Valderrama, S. Rojas, W. Kläui

Cyclometallation reactions in complexes of the type Rh(oq)(CO)(P(o-BrC6F4)Ph2) : II. The molecular structure of [F4)Ph2)(H2O)]2 (oq = 8-oxyquinolinate) Pages 375-384 Francisco Barceló, Pascual Lahuerta, M. Angeles Ubeda, Concepción Foces-Foces, Felix H. Cano and, Martín Martinez-Ripoll

Modification of the acid-base properties of hydroxycarbonyl complexes of iridium(III) by substitution of carbon monoxide by a tertiary phosphine ligand Pages 385-390 Antony J. Deeming, Graeme P. Proud

Catalyse chimique par le systeme nickel-2,2′-bipyridine de la reduction electrochimique d'halogenures aliphatiques Pages 391-400 Salah Mabrouk, Sylvain Pellegrini, Jean-Claude Folest, Yolande Rollin, Jacques Perichon

Complexes of functional phosphines : IX. Palladium and rhodium complexes with [R2PCH2CO2]- (R = Ph, c-C6H11) ligands. Crystal and molecular structure of [(o-}] Pages 401-410 Pierre Braunstein, Dominique Matt, Dominique Nobel, Salah-Eddine Bouaoud and, Daniel Grandjean